1. Kinetic theory and Ideal gases Flashcards

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1
Q

Assumptions for ideal gases

A
  1. A random distribution of energy between particles
  2. The particles behave as perfectly elastic spheres
  3. The volume of each molecule is negligible compared to the volume of the container
  4. There are no intermolecular forces
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2
Q

Pressure equation

A

pressure = force / area

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3
Q

total mass of a gas equation

A

number of moles x molar mass (Nm)

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4
Q

Density equation

A

mass / volume

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5
Q

Pressure of a gas equation

A

1/3 x NM/v x c²
1/3 x density x c²

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6
Q

rms speed

A

root mean square speed

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7
Q

number of moles equation

A

number in room / avagadros constant

total mass / molar mass

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8
Q

molar mass

A

relative molecular mass / 1000

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9
Q

Unit of temperature

A

Kelvin = +273 *C

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10
Q

Boyles law

A

pressure is equal to the inverse of volume when temperature is constant

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11
Q

Charles law

A

volume is proportional to temperature for a fixed mass and constant pressure

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12
Q

Pressure law or Gay -lussac Law

A

Pressure is directly proportional to temperature for a constant volume

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13
Q

Ideal gas equation

A

pV = nRT

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14
Q

Changes in gas equations

A

p1V1 / n1T1 = p2V2 / n2T2

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15
Q

Total energy in a gas

A

1.5 x n x R x T (R= 8.31)
or
1.5 x n x k x T (k= 1.38x10^-23)

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16
Q

internal energy definition

A

the combination of both kinetic energy of all of the particles and all the potential energy of particles

17
Q

Temperature defintion

A

measure of the average kinetic energy of all the particles in a substance

17
Q

Heat defintion

A

the energy transferred from a hot object to a cold object

18
Q

zeroth law of thermo

A

if two systems are in equilibrium with a third system then they are all in equilibrium with each other

19
Q

first law of thermo

A

the change in the internal energy of a system is equal to the heat supplied to the system minus the work done to the system

20
Q

first law equation

A

change in U = Q - W

21
Q

work done by a gas equation

A

W = pressure x change in volume

22
Q

if change in volume is positive …

A

the gas is expanding and doing work
Work is done by the gas itself

23
Q

if change in volume is negative …

A

the gas is contracting and work is being done to it

24
Q

when Q is positive

A

heat flows into the system

25
Q

when Q is negative

A

heat flows out of the system

26
Q

what is the area under a pressure volume graph

A

work done

27
Q

when volume increases and pressure is constant

A

temperature must also increase as work is done by the gas

28
Q

when pressure decrease and volume is constant

A

work done = 0
temperature decreased

29
Q

when volume decreases and pressure is constant

A

work is done on the gas
temperature decreases

30
Q

When pressure increases and volume is constant

A

Work done = 0
temperature must increase

31
Q

if the thermodynamic cycle is closed then…

A

the change in internal energy = 0
so net work done = net heat flow

32
Q

Definition of a gas

A

The state of a substance which expands to fill any volume

33
Q

What are the steps to derive the ideal gas law equation

A

Calculate:
1. Momentum
2. Time
3. Force
4. Pressure
5. Mean square speed

34
Q

Favourite icecream

A

Choc
Vanilla
Straw
Cookies n cream
Mint