01 to 04 Flashcards
For any system at equilibrium, the number of independent variables that must be arbitrarily fixed to establish its intensive state or degrees of freedom of the nonreacting systems.
Phase Rule
What is the equation for phase rule?
F = 2 - π + N
In F = 2 - π + N, what is π refers to?
number of phases
In F = 2 - π + N, what is N refers to?
number of chemical species
Who proposed the phase rule and in what year?
J.W. (Josiah Willard) Gibbs, 1875
It is a homogeneous region of matter. A gas or a mixture of gases, a liquid or a liquid solution, and a crystalline solid are examples.
Phase
Various phases can coexist, but on what condition must it possess for the phase rule to apply?
It must be in equilibrium
What is the minimum number of degrees of freedom for any system?
0
What is π and N at the triple point?
π=3, N=1
How many degrees of freedom has in liquid water in equilibrium with its vapor?
F = 2 - π + N
F = 2 - 2 + 1
F = 1
How many degrees of freedom has in a liquid solution of alcohol in water in equilibrium with its vapor?
F = 2 - π + N
F = 2 - 2 + 2
F = 2
It is found in the sub-cooled liquid and the superheated-vapor regions.
Isotherms