01 to 04 Flashcards

1
Q

For any system at equilibrium, the number of independent variables that must be arbitrarily fixed to establish its intensive state or degrees of freedom of the nonreacting systems.

A

Phase Rule

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2
Q

What is the equation for phase rule?

A

F = 2 - π + N

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3
Q

In F = 2 - π + N, what is π refers to?

A

number of phases

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4
Q

In F = 2 - π + N, what is N refers to?

A

number of chemical species

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5
Q

Who proposed the phase rule and in what year?

A

J.W. (Josiah Willard) Gibbs, 1875

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6
Q

It is a homogeneous region of matter. A gas or a mixture of gases, a liquid or a liquid solution, and a crystalline solid are examples.

A

Phase

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7
Q

Various phases can coexist, but on what condition must it possess for the phase rule to apply?

A

It must be in equilibrium

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8
Q

What is the minimum number of degrees of freedom for any system?

A

0

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9
Q

What is π and N at the triple point?

A

π=3, N=1

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10
Q

How many degrees of freedom has in liquid water in equilibrium with its vapor?

A

F = 2 - π + N
F = 2 - 2 + 1
F = 1

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11
Q

How many degrees of freedom has in a liquid solution of alcohol in water in equilibrium with its vapor?

A

F = 2 - π + N
F = 2 - 2 + 2
F = 2

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12
Q

It is found in the sub-cooled liquid and the superheated-vapor regions.

A

Isotherms

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