. Flashcards
‘Like dissolves ________’
Like
[Effect of Temperature on Solid in Liquid] When solubility increase as temp. increases the dissolution is________
Endothermic
Example: KCl, NaCl, NaNO3
[Effect of Temperature on Solid in Liquid] When solubility decrease as temp. increases the dissolution is________
Exothermic
Example: Na2CO3.H2O, Cerium Sulphate (Ce(SO4)3)
[Effect of Temperature on Solid in Liquid] Why does solubility does not continuously increase or decrease as temp. increases?
Because polymorphic/hydrated form changes to another
What is the effect of Pressure on solid in liquid solution?
no effect
[Gas in Liquid] Factor which affect the solubility of H2, He, N2 in H2O.
have small size therefore require less energy to vibrate.
[Effect of temperature Gas in Liquid] Dissolution if Gas in liquid is _______
Exothermic
[Effect of temperature Gas in Liquid] Solubility of some inert gases and H2 _____________ with increase in temp.
increases
[Effect of Pressure Gas in Liquid] State Henry’s Law
The partial pressure applied by any gas on a liquid surface is directly proportional to itsmole fractionpresent in a liquid solvent.
P= KHX
[Effect of Pressure Gas in Liquid] Relation between Henry’s constant and solubility.
Solubility ∝ 1/ KH
[Effect of Pressure Gas in Liquid] Unit of KH is
Same as Pressure
[Effect of Pressure Gas in Liquid] Relation between Henry’s constant and Temperature.
Temp ∝ KH
[Effect of Pressure Gas in Liquid] Conditon when Henry’s law is followed.
Pressure and Temperature is not too high.
Gas should not chemically react with solvent or not dissociate.
[Effect of Pressure Gas in Liquid] Gas responsible for Bends.
N2
[Effect of Pressure Gas in Liquid] Composition of gas in diver’s cylinder.
56.2% N2
11.7% He
32.1% O2