. Flashcards

1
Q

‘Like dissolves ________’

A

Like

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2
Q

[Effect of Temperature on Solid in Liquid] When solubility increase as temp. increases the dissolution is________

A

Endothermic
Example: KCl, NaCl, NaNO3

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3
Q

[Effect of Temperature on Solid in Liquid] When solubility decrease as temp. increases the dissolution is________

A

Exothermic
Example: Na2CO3.H2O, Cerium Sulphate (Ce(SO4)3)

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4
Q

[Effect of Temperature on Solid in Liquid] Why does solubility does not continuously increase or decrease as temp. increases?

A

Because polymorphic/hydrated form changes to another

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5
Q

What is the effect of Pressure on solid in liquid solution?

A

no effect

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6
Q

[Gas in Liquid] Factor which affect the solubility of H2, He, N2 in H2O.

A

have small size therefore require less energy to vibrate.

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7
Q

[Effect of temperature Gas in Liquid] Dissolution if Gas in liquid is _______

A

Exothermic

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8
Q

[Effect of temperature Gas in Liquid] Solubility of some inert gases and H2 _____________ with increase in temp.

A

increases

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9
Q

[Effect of Pressure Gas in Liquid] State Henry’s Law

A

The partial pressure applied by any gas on a liquid surface is directly proportional to itsmole fractionpresent in a liquid solvent.
P= KHX

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10
Q

[Effect of Pressure Gas in Liquid] Relation between Henry’s constant and solubility.

A

Solubility ∝ 1/ KH

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11
Q

[Effect of Pressure Gas in Liquid] Unit of KH is

A

Same as Pressure

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12
Q

[Effect of Pressure Gas in Liquid] Relation between Henry’s constant and Temperature.

A

Temp ∝ KH

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13
Q

[Effect of Pressure Gas in Liquid] Conditon when Henry’s law is followed.

A

Pressure and Temperature is not too high.
Gas should not chemically react with solvent or not dissociate.

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14
Q

[Effect of Pressure Gas in Liquid] Gas responsible for Bends.

A

N2

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15
Q

[Effect of Pressure Gas in Liquid] Composition of gas in diver’s cylinder.

A

56.2% N2
11.7% He
32.1% O2

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16
Q

Vapour pressure does and does not depend on
1. Amount of Liquid
2. Temp.
3. Nature of Liquid
4. Shape and size of vessel

A

Depends on 1. and 4
Does not depend on 2 and 3

17
Q

Relation between inter molecular forces of attraction in liquid and vapour pressure.

A

Inter molecular forces of attraction in liquid ∝ 1/vapour pressure.

18
Q

Clauius Clapeyron Equation

A

Log(P2/ P1) = ΔHV/2.303R (1/T1 - 1/T2 )

19
Q

Standard Boiling Point

A

Pext = 1 bar

20
Q

Normal Boiling Point

A

Pext = 1 atm

21
Q

State Raoult’s Law

A

The paritial V.P. of each component of a solution at constant temperature is directly proportional to its mole fraction
PA = PAo XA

22
Q

Graph of Raoult’s Law when B is more Volatile

A

https://www.google.com/url?sa=i&url=https%3A%2F%2Funacademy.com%2Fcontent%2Fupsc%2Fstudy-material%2Fchemistry%2Fwhat-is-raoults-law%2F&psig=AOvVaw1O_gglteV22PaG-a0hzjcw&ust=1712981636143000&source=images&cd=vfe&opi=89978449&ved=0CBIQjRxqFwoTCLCmvIPou4UDFQAAAAAdAAAAABAE

23
Q

Dalton’s Law Equation

A

PA = PT YA

24
Q

Resulting equation of Dalton and Raoult’s Law.

A

YA/ PAo + YB/ PBo = 1/ PT