. Flashcards

1
Q

describe SN2 rxns

A

d

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2
Q

describe SN1 rxns

A
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3
Q

Describe E2 rxns

A
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4
Q

describe E1 rxns

A
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5
Q

internal alkynes from terminal alkynes

A
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6
Q

describe addition of X2

A

carbocation stability
none of the cis-product
backside attack

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7
Q

describe addition of X and OH

A

CL2 or Br2 with H2O
make enantiomers

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8
Q

describe addiiton of H and OH

A

strong acid with first with the H - attaches to the less substituted carbon
H2O gives OH to the most substituted carbon

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9
Q

descruve addition of BH3

A

gives oppostie of markovnikovs product
1. BH3 with 2.H2O2, NaOH

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10
Q

Addition of H2 and partial reduction

A

H2 with a catalysis Pd/c or Pt (PtO2)
partial reduction with quinoline (Lindlar’s catalysis)

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11
Q

explain fomation of epoxides

A

using mCPBA, H+, H2O

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11
Q

formation of expocises with OsO4 and KMnO4

A
  • same thing with OsO4 and NaHSO3 and H2O
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