Chemical Changes Flashcards
Range of pH scale
0 to 14
What is lower on pH scale
More acidic solutions
What is higher on pH scale
More alkaline solutions
pH of neutral substances
7
What do you use to measure pH of a solution
An indicator
Indicator
Dye that changes colour depending on whether it’s above or below a certain pH
Wide range indicator
Indicator that contains a mixture of dyes so they gradually change colour over a broad range of pH
Example of wide range indicator
Universal indicator
Colour of acidic solutions on universal indicator
Orange-red
Colour of alkaline solution on universal indicator
Blue-purple
Colour of neutral solution on universal indicator
Green
How to measure pH electronically
- pH probe and pH meter
- probe placed in solution, meter gives numerical value of pH
More accurate method of measuring pH
pH probe and pH indicator
Acid
Substance that forms aqueous solutions with pH less than 7
What ions do acids form in water
H⁺
Base
A substance with pH greater than 7
Alkali
Base that dissolves in water to form a solution with pH greater than 7
What ions do alkalis form in water
OH⁻
Neutralisation
Reaction between acid and base
Neutralisation reaction word equation
acid + base —> salt + water
Neutralisation reaction between acids and alkalis symbol equation
H⁺ + OH⁻ —> H₂O
What happens when an acid/alkali neutralise each other
Products will be neutral with pH 7
What happens to strong acids in water
- ionise completely
- all acid particles dissociate to release H⁺ ions
What happens to weak acids in water
- do not fully ionise
- small proportion of acid particles dissociate to release H⁺ ions
Is ionisation of weak acids reversible
Yes
Why is ionisation of weak acids reversible
- reaction sets up equilibrium between undissociated and dissociated acid
as only a few acids particles release H⁺, equalibrium position lies well to left
Which kind of acid is more reactive
Stronger ones
Why are stronger acids more reactive
Higher concentration of H⁺ ions increases reactivity
pH
Measure of concentration of hydrogen (H⁺) ions in a solution
What happens to concentration of H⁺ ions as pH decreases by 1
It increases by a factor of 10
Formula for factor of change in H⁺ ion concentration
Factor H⁺ ion concentration changes by = 10⁻ˣ
X = change in pH
Acid strength
Proportion of acid molecules that ionise in water
Acid concentration
How much acid there is in a certain volume of water
How does acid concentration affect pH
pH decreases as acid concentration increases
Metal bases
- metal oxide
- metal hydroxide
- metal carbonate
Do metal oxides dissolve in water
Yes
Do metal hydroxides dissolve in water
Yes
Acid + metal oxide —>
Salt + water
Acid + metal hydroxide —>
Salt + water
Acid + metal carbonate —>
Salt + water + carbon dioxide
Making salts practical
- pick right acid and insoluble base
- gently warm dilute acid with Bunsen burner, turn off
- add insoluble base to acid a bit at a time until no more reacts - base is in excess and sinks to bottom of flask after stirring as all acid has been neutralised
- filter out excess solid to get salt solution
- pure/solid salt crystals - gently heat solution in water bath to evaporate some water, stop, leave solution to cool, crystals form to be filtered + dried
What is reactivity series
List of metals in order of reactivity towards other substances
Reactivity series
- potassium
- sodium
- calcium
- magnesium
- aluminium
- carbon
- zinc
- iron
- lead
- tin
- hydrogen
- copper
- silver
- gold
- platinum
What determines reactivity of metals
How easily they lose electrons - forming positive ions
What happens when metals react with water or acid
Lose electrons - forming positive ions
Acid + metal —>
Salt + hydrogen
What indicates speed of reaction between acid and metal
Rate at which bubbles of hydrogen are given off
How to more reactive metals react
- faster
- explosively
How do less reactive metals react
- slower
- less violently
Metal + water —>
Metal hydroxide + hydrogen
Which metals will react with water
More reactive ones
Oxidation in terms of oxygen
- metals reacting with oxygen to form oxides
- gain of oxygen
Reduction in terms of oxygen
- reaction that separates a metal from it’s oxide
- loss of oxygen
How can some metals be extracted by reduction with carbon
- metal reacted with carbon
- ore is reduced as oxygen is removed from it
- carbon gains oxygen and is oxidised
Which metals are extracted by electrolysis
Metals above carbon on reactivity series
Which metals are extracted by reduction using carbon
Metals below carbon on reactivity series
Why are some elements mined in elemental form
They are so unreactive
Oxidation in terms of electrons
Loss of electrons
Reduction in terms of electrons
Gain of electrons
Redox reaction
Reaction where reduction and oxidation happen at the same time
Displacement reaction
Redox reaction where a more reactive metal displaces a less reactive metal from its compound
Why are displacement reactions redox reactions
- metal ion gains electrons - reduced
- metal atom loses electrons 0 oxidised
Electrolysis equipment
- beaker
- electrolyte solution
- anode
- cathode
- wire + power source
Electrolyte solution
Liquid/solution containing ionic compound - electrons free to move
Electrodes
Solid conductors
Anode charge
Positive
Cathode charge
Negative
What does electrolysis mean
Splitting up with electricity
Versions of electrolysis
- electrolysis of molten substance
- electrolysis of aqueous solution
How does electrolysis split up molten compounds
- electric current flows through electrolyte
- ions attracted to electrodes
- ions discharged at electrodes
What happens at anode
Oxidation
What happens at cathode
Reduction
Oxidation
- loss of electrons
- gain of oxygen
Reduction
- gain of electrons
- loss of oxygen
Which process occurs first in electrolysis
Oxidation
What happens after oxidation in electrolysis
Electrons travel through wire from anode to cathode for reduction
Why is it preferable to extract metals through displacement with carbon
Cheap
When is electrolysis used to extract metals from metal oxide
When metal more reactive than carbon
Downsides of electrolysis
Requires much energy so expensive
Why is aluminum oxide not ready for electrolysis straight away
- electrolysis needs ions free to move
- aluminum oxide solid - ions fixed
How to prepare aluminum oxide for electrolysis
- purify bauxite into Al₂O₃
- mix Al₂O₃ with cryolite mineral - lowers melting point
- melt Al₂O₃ to become molten - ions free to move
When is electrolysis of aqueous solution used
When substance being separated is soluble - dissolved in water (easy to do)
What is always present from water in electrolysis of aqueous soltion
- H⁺ ions
- OH⁻ ions
Which ions from water go to anode
OH⁻
Which ions from water go to cathode
H⁺
Aqueous electrolysis rules at anode
- group 7 metal - gets discharged
- NO group 7 metal -OH⁻ gets discharged
Aqueous electrolysis rules at cathode
Least reactive gets discharged
H⁺ half equation
2H⁺ + 2e⁻ –> H₂
OH⁻ half equation
4OH⁻ –> 2H₂O + O₂ + 4e⁻