1.5 Kinetics Flashcards
What does a reaction need to occur
Energy greater than or equal to the activation energy, and correct particle orientation
What must remian constant, in the Maxwell-Boltzmann distribution
The area under the graph (molecules in the sample)
What are 5 ways to increase rate of rection
- Increase Pressure (gas only)
- Increase temperature
- Increase concentration
- Add a catalyst
- Increase surface area
Explain how increasing surface area has an effect on rate of reaction
Increase SA
More chance of collisions
More frequent collisions lead to increase rate of reaction
Explain how increasing temperature has an effect on rate of reaction
Increase temperature
Particles have more thermal / kinetic energy
So they move faster
Increasing chance of collisions
and also the force of collisions
How does increasing the temp affect the Maxwell-Boltzmann curve
Shifts it to the right
Broader and flatter
Constant area under graph
How do catalyst work
Lower the activation energy by finding an alternative reaction pathway
Name and explain the two types of catalysts
- Heterogenous Catalysts - same phase as reactants
- Homogenous catalysts - diff phase to reactants
Explain how increasing concentration has an effect on rate of reaction
Increasing conc.
More molecules in a given volume
Collisions more likely
(same for pressure tbh)
How does increasing the pressure/conc. affect the Maxwell-Boltzmann curve
Peaks higher
But the shape is the same
Constant area under the graph
How does a catalyst affect the Maxwell-Boltzmann distribution
Shape is unchanged
The activation energy (Ea) is shifted to the left