Synthetic Routes - Aliphatic Flashcards

1
Q

alkane to haloalkane

A

halogen UV

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

alkene to alkane

A

H2 / Ni

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

alkene to haloalkane

A

hydrogen halide - halogenation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

alkene to alcohol

A

H20 (steam) / H3PO4

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

alcohol to alkene

A

H3PO4 or H2SO4, heat - dehydration

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

haloalkane to nitrile

A

CN- / ethanol

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

haloalkane to amine

A

NH3 / ethanol

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

nitrile to amine

A

H2 / Ni - reduction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

haloalkane to alcohol

A

NaOH(aq)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

alcohol to haloalkane

A

sodium halide / H2SO4

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

secondary alcohol to ketone

A

K2Cr2O7 / H2SO4, reflux - oxidation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

ketone to secondary alcohol

A

NaBH4 - reduction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

ketone to hydroxynitrile

A

NaCN(aq) / H+(aq)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

primary alcohol to aldehyde

A

K2Cr2O7 / H2SO4, distillation - oxidation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

aldehyde to primary alcohol

A

NaBH4 - reduction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

aldehyde to hydroxynitrile

A

NaCN(aq) / H+(aq)

17
Q

primary alcohol to carboxylic acid

A

K2Cr2O7 / H2SO4, reflux

18
Q

aldehyde to carboxylic acid

A

K2Cr2O7/ H2SO4, reflux

19
Q

alcohol to ester

A

carboxylic acid / concentrated H2SO4 OR acid anhydride - condensation

20
Q

ester to carboxylate

A

OH-, heat

21
Q

ester to carboxylic acid

A

dilute acid, heat

22
Q

carboxylic acid to ester

A

alcohol / concentrated H2SO4 - condensation

23
Q

nitrile to carboxylic acid

A

H2O / HCl, heat - hydrolysis

24
Q

hydroxynitrile to carboxylic acid

A

H2O / HCl, heat - hydrolysis, acidification

25
Q

carboxylic acid to acyl chloride

A

SOCl2 - chlorination

26
Q

acyl chloride to carboxylic acid

A

H2O - hydrolysis

27
Q

acyl chloride to ester

A

alcohol

28
Q

acyl chloride to primary amide

A

NH3

29
Q

acyl chloride to secondary amide

A

primary amine

30
Q

hydroxynitrile to amine

A

H2 / Ni - reduction