Reactions by Product Flashcards
1
Q
ALCOHOL
A
- H2O, H+[Markovnikov, carbocation intermediate]
- Hg(OAc)2, H2O; 2. NaBH4 [Markovnikov, mercurinium intermediate, no rearrangement]
- BH3, THF; 2. H2O2, NaOH [anti-Markovnikov, syn addition]
2
Q
PROTONATED ALCOHOL
A
- H—X [X=Cl, OSO3H, or any strong acid]
3
Q
PROTONATED THIOL
A
- H—X [X=Cl, OSO3H, or any strong acid]
4
Q
ALKOXIDE
A
- NaOH [or any strong base]
5
Q
THIOLATE
A
- NaOH [or any strong base]
6
Q
GRIGNARD REAGENT
[R—MgBr]
A
- R—Br, Mg, Et2O
7
Q
ORGANOLITHIUM
[R—Li]
A
- R—Br, 2 Li, Et2O
8
Q
DICHLOROCARBENE
[:C—Cl2]
A
- HCCl3, KOtBu [alpha elimination, solvent is HOtBu]
9
Q
CARBENOID (Simmons-Smith reagent)
[I—CH2—ZnI]
A
- Zn/Cu
10
Q
A
