Haloalkanes Flashcards
general formula for haloalkanes with one halogen bonded to it
Primary haloalkane
1 carbon atom
Secondary haloalkane
2 Carbon atoms
Tertiary haloalkane
3 carbon atom
bonding in haloalkanes
London forces and permanent dipole to dipole interactions
what doe haloalkanes react with
nucleophiles
what is a hydrolysis reaction an example of ?
Nucleophilic substitution
Conditions for nucleophilic substitution
we add ethanol beuse haloalkanes are insoluble in water. Ethanol solubilies haloalkanes so they can react with the nucleophile
60 degrees
nucleophilie sub with chloromethane and hydroxide ion
The Rate of Hydrolysis of Haloalkanes by Nucleophilic Substitution
in a testube place 1cm of ethanol using a piipet
then add 0.1cm^3 of your haloalkane to each test tube
heat in a water bath at 60 degrees celsius
then in a separate test tube add aqueous silver nitrate. Then place in the same water bath
the wait for 10 mins for all the solutions to reach the same temp
the add 1 cm^3 of aquesos silvernitarte to each of the test tube.
white cream yellow
iodine forms first then
bromom
then chloro alkane
Why do we use water ions for hydrolysis instead of hydroxide ions
Because hydroxide ions react with silver nitrate to form insoluble silver hydroxide
whats a nuclophile
(an
electron pair donor