Haloalkanes Flashcards

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1
Q

general formula for haloalkanes with one halogen bonded to it

A
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2
Q

Primary haloalkane

A

1 carbon atom

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3
Q

Secondary haloalkane

A

2 Carbon atoms

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4
Q

Tertiary haloalkane

A

3 carbon atom

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5
Q

bonding in haloalkanes

A

London forces and permanent dipole to dipole interactions

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6
Q

what doe haloalkanes react with

A

nucleophiles

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7
Q

what is a hydrolysis reaction an example of ?

A

Nucleophilic substitution

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8
Q

Conditions for nucleophilic substitution

A

we add ethanol beuse haloalkanes are insoluble in water. Ethanol solubilies haloalkanes so they can react with the nucleophile

60 degrees

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9
Q

nucleophilie sub with chloromethane and hydroxide ion

A
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10
Q

The Rate of Hydrolysis of Haloalkanes by Nucleophilic Substitution

A

in a testube place 1cm of ethanol using a piipet

then add 0.1cm^3 of your haloalkane to each test tube

heat in a water bath at 60 degrees celsius

then in a separate test tube add aqueous silver nitrate. Then place in the same water bath

the wait for 10 mins for all the solutions to reach the same temp

the add 1 cm^3 of aquesos silvernitarte to each of the test tube.

white cream yellow

iodine forms first then
bromom
then chloro alkane

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11
Q

Why do we use water ions for hydrolysis instead of hydroxide ions

A

Because hydroxide ions react with silver nitrate to form insoluble silver hydroxide

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12
Q

whats a nuclophile

A

(an
electron pair donor

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