Final exam Flashcards

1
Q

what is an amino group

A

NH2

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2
Q

when it comes to aromaticity what does an even huckle number mean versus an odd one

A

even: antiaromatic odd: aromatic

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3
Q

what is merkovnikov addition and anti-merkovnikov

A

merkovnikov addition when the nucleophile attacks more substituted carbon
anti-merkovnikov when the nucleophile attacks less substituted carbon

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4
Q

what reagent would cause merkovnikov addition to alkene

A

h2o/h+

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5
Q

what kind of bonds (sigma and pi) do single, double, and triple bonds have

A

single: 1 sigma
double: 1 sigma and 1 pi
triple: 1 sigma and 2 pi

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6
Q

what bond angle does a trigonal planar molecule have?

A

120

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7
Q

how do you turn a 2 prime alcohol into a ketone

A

using crO3/H+

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8
Q

the reaction of an ester with a Grignard reagent followed by the addition of acid will usually produce….

A

a tertiary alcohol

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9
Q

what does NaBH4 react with

A

aldehyde ketone and acid chloride

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10
Q

how to make an oxime from a ketone?

A

NH2OH

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11
Q

how do you turn a ketone into a secondary alcohol

A

raney nickle

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12
Q

What does LDA do (4 things)

A
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13
Q

how do you convert primary alcohol into aldehyde and secondary alcohol into a ketone

A

PCC

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