Chapter 3 Flashcards

Quantum Theory and the Electronic Structure of Atoms

1
Q

Series of elements that has partially filled 5f and/or 6d subshells.

A

Actinide series

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2
Q

The vertical distance from the midline of a wave to the top of the peak or the bottom of the trough.

A

Amplitude

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3
Q

Describes the shape of the atomic orbital

A

Angular momentum quantum number (ℓ)

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4
Q

The wave function of an electron in an atom

A

Atomic orbital

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5
Q

The process by which the periodic table can be built up by successively adding one proton to the nucleus and one electron to the appropriate atomic orbital.

A

Aufbau principle

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6
Q

The electromagnetic radiation emitted from a heated solid.

A

Blackbody radiation

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7
Q

Energy stored within the structural units (molecules or polyatomic ions) of chemical substances.

A

Chemical energy

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8
Q

Atomic orbital in which the angular momentum quantum number is 2.

A

d orbital

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9
Q

A wavelength calculated using the following equation: λ = h/mu

A

de Broglie wavelength

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10
Q

Having equal energy

A

Degenerate

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11
Q

A species without unpaired electrons that is weakly repelled by magnetic fields.

A

Diamagnetic

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12
Q

Consists of radio waves, microwave radiation, infrared radiation, visible light, ultraviolet radiation, X rays, and gamma rays.

A

Electromagnetic spectrum

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13
Q

A wave that has an electric field component and a magnetic field component.

A

Electromagnetic wave

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14
Q

The distribution of electrons in the atomic orbitals of an atom.

A

Electron configuration

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15
Q

The probability that an electron will be found in a particular region of an atom.

A

Electron density

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16
Q

The fourth quantum number that differentiates two electrons in the same orbital.

A

Electron spin quantum number (ms), either +(1/2) or -(1/2)

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17
Q

The potential energy that results from the interaction of charged particles.

A

Electrostatic energy

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18
Q

the light emitted, either as a continuum or in discrete lines, by a substance in an excited electronic state.

A

Emission spectrum

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19
Q

The capacity to do work or transfer heat

A

Energy

20
Q

A state that is higher in energy than the ground state.

A

Excited state

21
Q

Atomic orbital in which the angular momentum quantum number is 3.

A

f orbital

22
Q

The number of waves that pass through a particular point in 1s.

A

Frequency (v)

23
Q

The lowest energy state of an atom.

A

Ground state

24
Q

It is impossible to know simultaneously both the momentum and the position of a particle with certainty.

A

Heisenberg uncertainty principle

25
Q

The most stable arrangement of electrons in orbitals of equal energy is the one in which the number of electrons with the same spin is maximized.

A

Hund’s rule

26
Q

The SI unit of energy

A

Joule (J)

27
Q

The energy that results from motion

A

Kinetic energy

28
Q

A series of 14 elements that have incompletely filled 4f subshells or that readily give rise to cations that have incompletely filled 4f subshells.

A

Lanthanide (rare earth) series

29
Q

First law of thermodynamics stating that energy can be neither created nor destroyed.

A

Law of conservation of energy

30
Q

The emission or absorption of light only at discrete wavelengths.

A

Line spectrum

31
Q

Describes the orientation of an orbital in space.

A

Magnetic quantum number (mℓ)

32
Q

A representation in an electron configuration that shows in brackets the most recently completed noble gas.

A

Noble gas core

33
Q

A point at which a standing wave has zero amplitude; points at which electron density in an atom is zero.

A

Node

34
Q

Atomic orbital in which the angular momentum quantum number is 1

A

p orbital

35
Q

No two electrons in an atom can have the same four quantum numbers

A

Pauli exclusion principle

36
Q

A phenomenon in which electrons are ejected from the surface of a metal exposed to light of at least a certain minimum frequency.

A

Photoelectric effect

37
Q

A quantum of light

A

Photon

38
Q

The energy possessed by an object by virtue of its position

A

Potential energy

39
Q

Designates the size of the orbital.

A

Principal quantum number (n)

40
Q

The smallest quantity of energy that can be emitted (or absorbed) in the form of electromagnetic radiation

A

Quantum

41
Q

Numbers required to describe the arrangement of electrons in an atom

A

Quantum numbers

42
Q

Atomic orbital in which the angular momentum quantum number is 0.

A

s orbital

43
Q

The energy associated with the random motion of atoms and molecules

A

Thermal energy

44
Q

The minimum frequency of light required to eject an electron from the surface of a metal in the photoelectric effect

A

Threshold frequnecy

45
Q

The distance between identical points n successive waves.

A

Wavelength λ

46
Q

Tiny, indivisible “packages” of energy.

A

Quanta (Plural of Quantum)

47
Q

Atoms with electron configurations in which there are one or more unpaired electrons.

A

Paramagnetic