Buffers Flashcards
What is a buffer?
solution that maintains a constant pH despite the addition of acid/base/water
What is the pH of an acidic buffer?
below 7
What is the pH of a basic buffer?
above 7
What is an acidic buffer?
a weak acid and its salt
How can an acidic buffer be made by adding acid to salt?
adding a solution of the salt to the weak acid (vice versa)
the salt dissociates completely and the acid slightly
How can you make an acidic buffer by partial neutralisation?
by adding a strong base to the weak acid
- the salt is made as a product
Where does equilibrium moves if H+ are added
H+ reacts with A-
eqm moves to left to decrease moles of H+
Where does equilibrium moves if OH- ions are added?
alkali is added
they react with H+ forming H2O and eqm moves to right and more acid is dissociated to replace H+
What is the equation for making a buffer using weak acid and its salt?
Ka = [H+] [A-]
————-
[HA]
A- = moles of salt
HA= moles of acid
What effect does adding a strong acid have on a buffer
Increases moles of HA
Decreases moles of A-
What effect does adding a strong base have on a buffer?
Decreases moles of HA
Increases moles of A-