Alkanes Flashcards

1
Q

What is a combustion reaction?

A

When something burns in oxygen, to produce heat energy.

It is exothermic

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2
Q

what is complete combustion?

A

when a substance completely burns in oxygen.

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3
Q

what are the products of complete combustion?

A

carbon dioxide and water.

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4
Q

what is an incomplete combustion?

A

when a substance combusts, but not completely, because of a lack of oxygen.

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5
Q

what are the products of incomplete combustion?

A

Always water, ans sometimes Carbon monoxide or solid carbon

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6
Q

what is a pollutant?

A

when a substance causes a negative effect on the planet.

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7
Q

what are the pollutants of complete combustion?

A

CO2 and H2O

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8
Q

explain how CO2, and H2O lead to global warming.

A

CO2 and H20 absorb UV light from the sun, therefore the temperature on earth increases.

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9
Q

What are some of the pollutants from incomplete combustion? and waht are their effects?

A

carbon monoxide, which is flammable and toxic to humans.

engines in cars produce carbon monoxide.

Solid carbon ( also called soot) can lead to smog.

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10
Q

why does complete combustion, produce more energy than incomplete?

A

becuase the majority of the energy, comes from the formation of the carbon dioxide.

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11
Q

why is complete combustion more efficient, than incomplete combustion?

A

Because we need to burn less fuel, tp produce the same ammount of energy.

Since we need less fuel, it is also more cheaper.

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12
Q

what are the three organic compound equations that you need to remember?

A
  1. CH4S + 302—->CO2+2H20+ SO2

2.CH4N+ 2.5O2—->CO2+2H2O+NO

3.CH4Si +3O2—->CO2 + 2H20 + SiO2

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13
Q

what is the main problem with releasing sulfur dioxide?

A

It causes breathing proboems, and respiratory issues.

also leads to acid rain.

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14
Q

How does SO2 produce acid rain?

A

SO2 + 2H2O—-> H2SO4

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15
Q

What is an unburnt hydrocarbon?

A

When alkanes in petrol, dont undergo combustion, and instead are released as gases, we call them unburnt hydrocarbons.

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16
Q

whay do unburnt hydrocarbons release? and what is its effects?

A

smog. it prevents sunlight from reaching crops.

17
Q

what 3 processes happen in a petrol engine? and state all the products.

A
  1. incomplete combustion : C (s), CO, H2O.
  2. Complete combustion: CO2, H2O.
  3. unburnt hydrocarbons : smog.
18
Q

describe hiw nitric oxide forms and what it does to the environment. Include some equations in your answers.

A

Since there is alot of high heat in a petrol engine, other side reactions may occur.

-N2+O2—-> 2NO

It creates respiratory issues, and acid rain.

19
Q

what do we use in order to reduce the pollution from engines in cars?

A

catalytic converters.

20
Q

describe how a catalytic converter, helps prevent the number of unburns hydrocarbon, NO and CO.

A

unburnt hydrocarbon + O2—-> CO2 + H2O.

2NO + 2CO —-> N2 + 2CO2

21
Q

what is crude oil?

A

Oil that hasnt had its impurities removed yet. The oil still contains many different alkanes, with many different properties.

22
Q

Describe how fractional distillation is carried out, in order to separate alkanes from crude oil.

A

step 1: pass the crude oil, through a furnace.
- the furnace will turn it from a liquid to a vapour.
- step 2: This vapour then passes into the bottom of a huge collumn.
- the bottom of this collumn is super hot, but the top isnt. ( so temperature decreases as we go up a collumn).
- step 3: When the vapour reaches the temperature of its boiling point, it then condenses back into a liquid, and gets in a collection chamber in a DIFFERENT fraction.

23
Q

state what happens to the boiling point when an alkane increases in size. and waht does this mean in fractional distillation?

A

Number of wan der waals forces increases, which means that more energy required to break bond, thus higher boiling point.

It means the larger alkanes will condense, lower in the collumn.

24
Q

what is cracking?

A

The process by which we conver longer chain hydrocarbons, into shiorter chain hydrocarbons.

25
Q

Why are short chain hydrocarbons, better than long chain hydrocarbons?

A

Because they are more flammable, since they burn more easily.

26
Q

What are the two types of cracking?

A

Thermal cracking, and catalytic cracking.

27
Q

state the conditiond needed for thermal cracking, and explain each one.

A

700 - 1000 C .

700 ATM / 7000 KPa.

Because alot of energy is required to break the bond enthalpy of the carbon carbon bond.

28
Q

What are the products of thermal cracking?

A

A shorter chain alkane, and one or more alkenes.

The total number of carbons and hydrogens, should add up to 0.

29
Q

what is the main type of alkane, produced in thermal cracking?

A

Mainly linear alkanes.

30
Q

What are the conditions for catalytic cracking?

A

requires a zeolite catalyst, slight pressure
( 1ATM/100KPa), and high tmperatures. ( 525 - 750C).

31
Q

what are the main products of catalytic cracking?

A

branched alkanes, cycloalkanes, or aromatics.

32
Q

contrast catalytic VS thermal cracking.

A

thermal: expensive due to high temperatures, and pressure.
Catalytic: expensive, because zeolite needs replacing.

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33
Q

what are some catalysts used in a catalytic converter?

A

Platinum , Palladium, Rhodium, Iridium.