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OrChem > Aliphatic Reactions > Flashcards

Aliphatic Reactions Flashcards

1
Q

CH3COOH —-> CH3COCl + POCl3 + HCl
▪︎Type of Reaction
▪︎Reagents and Conditions

A

Type: Preparation of acyl chloride
Reagents and Conditions:
PCl5
Room temp

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2
Q

CH3COOH —-> 3CH3COCl + H3PO3
▪︎Type of Reaction
▪︎Reagents and Conditions

A

Type: Prepare of acyl chloride
Reagents and Conditions:
PCl3
Heat

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3
Q

CH3COOH —-> CH3COCl + SO2 + HCl
▪︎Type of Reaction
▪︎Reagents and Conditions

A

Type: Preparation of acyl chloride
Reagents and Conditions:
SOCl2
Room temp

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4
Q

HCOOH + [O] —-> CO2 + H2O
▪︎Type of Reaction
▪︎Reagents

A 
Type: Oxidation 
Reagents:
Tollen's & Fehling's reagent
OR
KMnO4/H+
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5
Q

COOH–COOH [O] —-> CO2 +H2O
▪︎Type of Reaction
▪︎Reagents

A 
Type: Oxidation 
Reagents:
Tollen's & Fehling's reagent
OR 
KMnO4/H+
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6
Q

CH3COCl —-> CH3COOH + HCl
▪︎Type of Reaction
▪︎Reagents

A

Type: Nucleophilic substitution/ Addition-elimination reaction
Reagents:
H2O

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7
Q

CH3COCl —-> CH3CONH2 + HCl
▪︎Type of Reaction
▪︎Reagents and Conditions

A

Type: Nucleophilic substitution/ Addition-elimination
Reagents and Conditions:
NH3
aqueous

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8
Q

CH3COCl —-> CH3CONHCH3 + HCl
▪︎Type of Reaction
▪︎Reagents

A

Type: Nucleophilic substitution/ Addition-elimination
Reagents:
CH3NH2

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9
Q

CH3COCl —-> CH3COOCH3 + HCl
▪︎Type of Reaction
▪︎Reagents

A

Type: Nucleophilic substitution/Addition-elimination
Reagents:
CH3OH

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10
Q

CH3Br —-> CH3NH2 + HBr
▪︎Type of Reaction
▪︎Reagents and Conditions

A

Type: Preparation of amines
Reagents and Conditions:
Hot alcoholic NH3
Heat under pressure

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11
Q

CH3CN —-> CH3CH2NH2
▪︎Type of Reaction
▪︎Reagents

A

Type: Reduction
Reagents:
LiAlH4

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12
Q

CH3CONH2 —> CH3CH2NH2 + H2O
▪︎Type of Reaction
▪︎Reagents and Conditions

A

Type: Reduction
Reagents and Conditions:
LiAlH4
Dry ether

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13
Q

CH3CONH2 —-> CH3COOH + NH3
▪︎Type of Reaction
▪︎Reagents and Conditions

A

Type: Acid hydrolysis
Reagents and Conditions:
Dilute HCL
Heat

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14
Q

CH3CONH2 —-> CH3COO-Na+ + NH3
▪︎Type of Reaction
▪︎Reagents and Conditions

A

Type: Alkaline hydrolysis
Reagents and Conditions:
NaOH (aq)
Heat

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15
Q

CH3COOH —-> CH3COO-NH4+

▪︎Reagents

A

(NH4)2CO3

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16
Q

COOHCH2NH2 + COOHCH2NH2 —-> COOHCH2NH3+ + Na+COO- CH2NH2

▪︎Reagents

A

H+

NaOH

OrChem (2 decks)

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