Additions and & Hydration of alkenes Flashcards
What is an electrophile
Electron pair acceptor
Hydrogen halides
Symmetrical electrophilic addition of alkenes and halides
ethene and hydogenbromide
Markownikoff’s Rule for Electrophilic Addition to Alkenes that are asymmetrical.
- Secondary carbocation is more stable as it has 2 R groups and 1 hydrogen making it the MAJOR carbocation.
Markownikoff’s Rule - halides are more likely to form a minor product.
When a hydrogen halide reacts with an asymmetric alkene, the hydrogen atom of the halide is more likely to bond to the carbon atoms which is attached to the greater number of hydrogen atoms
Halogenens and Alkenes
Electrophilic addiction
broimne in alkene goes from orange and declourlies
Halogen reactions with alkenes vs Halide reactions with alkenes
state of water in hydartion of alkenes
Steam
Conditions of hydration to take place
Phosphoric acid catalyst H3PO 4
300 degrees celsius
60 atm
Hydration of alkenes
use an example with ethene
Conditions used for the hydrogenation of alkenes
Nickel catalyst
150 degrees celsius
Hydrogenation of an alkene adds 2 hydrogen atoms to the carbon-carbon double bond.
Vegetable oils are unsaturated and may be hydrogenated to make margarine, which has a higher melting point due to stronger London Dispersion Forces
Sulfuric acid and ethene electrophilicsub
Sulfuric acid and ethene hydration
Moni=omer
always has diuble boind betwwen carbn atoms