Addition reaction: Reagents Flashcards

1
Q

RCO3H

A

ANTI-DIHYDROXYLATION

OH OH ANTI

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2
Q

1) OsO4

—————————>

2) NaHSO3, H2O

A

SYN DYHYDROXILATION

OH OH SYN

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2
Q

mCPBA

———————>

H3O

A

ANTI-DIHYDROXYLATION

OH OH ANTI

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4
Q

1) Hg(AOc)2, H2O

————————->

2) NaBH4

A

OXYMERCURATION/DEMERCURATION

H OH mark

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5
Q

HX

(X=Br, CL, or I)

A

HYDROHALOGENATION

H X mark

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6
Q

X2

(X= Br or Cl)

A

HALOGENATION

X X ANTI

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7
Q

1) BH3

—————————>

2) H2O2, NaOH

A

HYDROBORATION

H OH non-mark SYN

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8
Q

H2

—————->

Pd/C

A

CATALYTIC HYDROGENATION

H H SYN

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9
Q

X2

————>

H2O

A

HALOHYDRIN FORMATION

X OH mark ANTI

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10
Q

H+

or

H2SO4

or

H3PO4

A

ACID-CATALYZED HYDRATION

H OH mark

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