Addition reaction: Reagents Flashcards
1
Q
RCO3H
A
ANTI-DIHYDROXYLATION
OH OH ANTI
2
Q
1) OsO4
—————————>
2) NaHSO3, H2O
A
SYN DYHYDROXILATION
OH OH SYN
2
Q
mCPBA
———————>
H3O
A
ANTI-DIHYDROXYLATION
OH OH ANTI
4
Q
1) Hg(AOc)2, H2O
————————->
2) NaBH4
A
OXYMERCURATION/DEMERCURATION
H OH mark
5
Q
HX
(X=Br, CL, or I)
A
HYDROHALOGENATION
H X mark
6
Q
X2
(X= Br or Cl)
A
HALOGENATION
X X ANTI
7
Q
1) BH3
—————————>
2) H2O2, NaOH
A
HYDROBORATION
H OH non-mark SYN
8
Q
H2
—————->
Pd/C
A
CATALYTIC HYDROGENATION
H H SYN
9
Q
X2
————>
H2O
A
HALOHYDRIN FORMATION
X OH mark ANTI
10
Q
H+
or
H2SO4
or
H3PO4
A
ACID-CATALYZED HYDRATION
H OH mark