Acid & Bases Flashcards
Sorenson PH scale.
Ka for acids and bases
Pka for acids and bases
PH of weak acids
titrations
Arrhenius definition of acid
acids are proton (H+) acceptors
bases hydroxyl ion (OH-) donors
HCL is acid in water but not in benzene (as it is not an aqeous environment)
ammonia (NH3) is a base with no hydroxyl group
Bronsted lowry definition
acid proton donor
base proton acceptor
HCL not ionised in benzene as does not accept proton
definition works with some non aqueous solutions like ethanol but is less good in aprotic solvents.
lewis definition
more general
lewis acid - electron pair acceptor
lewis base - electron pair donor
all bronsted lowry acids are lewis acids but not vice versa.
lewis definition metal cations are acids
group three elements are acids accordng to lewis.
how to determine strong/weak acid
strong acids: ↑ka value as [HA] is low and [A-] ↑
pKa most common way to measure strength
pKa = -log[Ka]
strong acids have a low Ka
how to determine strong/weak base
strong bases = ↑kb as [B] is low and [BH+]↑
pKa used to measure strength of base but by measuring the strength of its conjugate acid.
stronger base: weaker conjugate acid
low Ka
↑pKa