5.3 - 5.5 Flashcards
Back titration
Method where an excess of a reagent is reacted with a sample. The unreacted reagent is then determined by titration.
Rf values
Retardation factor, this is calculated using the expression:
Rf = Distance moved by spot
Distance moved by solvent
Retention time
The time taken from injection until a component reaches the detector.
Transition metal
An element which forms at least one stable ion with a partially filled d-subshell.
Complex
A central metal atom or ion with ligands bonded by co-ordinate bonds.
Ligand
An ion or molecule with a lone pair of electrons which forms a co-ordinate bond with a central metal atom or ion in a complex.
Co-ordination number
The number of co-ordinate bonds to a central metal atom or ion in a complex.
Monodentate
A ligand which uses only one lone pair of electrons to form a co-ordinate bond with a central metal atom or ion in a complex.
Bidentate
A ligand which uses two lone pairs of electrons to form two co-ordinate bonds with a central metal atom or ion in a complex.
Polydentate
A ligand which uses many lone pairs of electrons to form more than two co-ordinate bonds with a central metal atom or ion in a complex.