5.3 - 5.5 Flashcards

1
Q

Back titration

A

Method where an excess of a reagent is reacted with a sample. The unreacted reagent is then determined by titration.

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2
Q

Rf values

A

Retardation factor, this is calculated using the expression:
Rf = Distance moved by spot
Distance moved by solvent

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3
Q

Retention time

A

The time taken from injection until a component reaches the detector.

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4
Q

Transition metal

A

An element which forms at least one stable ion with a partially filled d-subshell.

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5
Q

Complex

A

A central metal atom or ion with ligands bonded by co-ordinate bonds.

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6
Q

Ligand

A

An ion or molecule with a lone pair of electrons which forms a co-ordinate bond with a central metal atom or ion in a complex.

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7
Q

Co-ordination number

A

The number of co-ordinate bonds to a central metal atom or ion in a complex.

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8
Q

Monodentate

A

A ligand which uses only one lone pair of electrons to form a co-ordinate bond with a central metal atom or ion in a complex.

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9
Q

Bidentate

A

A ligand which uses two lone pairs of electrons to form two co-ordinate bonds with a central metal atom or ion in a complex.

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10
Q

Polydentate

A

A ligand which uses many lone pairs of electrons to form more than two co-ordinate bonds with a central metal atom or ion in a complex.

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