25.4 disubstitution and directing groups Flashcards

1
Q

what sort of directing group is NH2?

A

2- and 4-

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2
Q

what sort of directing group is -NHR?

A

2- and 4-

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3
Q

what sort of directing group is RCOR?

A

3-

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4
Q

what sort of directing group is -OH?

A

2- and 4-

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5
Q

what sort of directing group is -OR?

A

2- and 4-

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6
Q

what sort of directing group is -R

A

2- and 4-

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7
Q

what sort of directing group is -C6H5?

A

2- and 4-

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8
Q

what sort of directing group is -CHO?

A

3-

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9
Q

what sort of directing group are halides?

A

2- and 4-

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10
Q

what sort of directing group is -COOH?

A

3-

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11
Q

what sort of directing group is -CN?

A

3-

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12
Q

what sort of directing group is -NO2?

A

3-

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13
Q

what are activating groups?

A

groups that makes the benzene ring react more readily with electrophiles

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14
Q

what are deactivating groups?

A

groups that makes the benzene ring react less readily with electrophiles

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15
Q

what is position 2 on the benzene ring also called?

A

ortho

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16
Q

what is position 3 on the benzene ring also called?

A

meta

17
Q

what is the position 4 on the benzene ring also called?

A

para

18
Q

are 2-, 4- directing groups activating or deactivating groups?

A

activating

19
Q

are 3- directing groups activating or deactivating groups?

A

deactivating

20
Q

how do groups activate the benzene ring?

A

donate electrons to the benzene ring

21
Q

how do groups deactivate the benzene ring?

A

withdraw electrons from the benzene ring